Modification of polyetherimide membranes with ZIFs fillers for CO2 separation
نویسندگان
چکیده
منابع مشابه
Synthesis of PIL membranes for CO2 separation
Carbon dioxide (CO2) can be commonly found in natural gas streams, biogas, flue gas and product of coal gasification[1]. The presence of CO2 and other acid gases reduce the thermal efficiency and make the gas streams become acidic and corrosive, which in turn reduces the possibilities of gas compression and the transport within the transportation systems[2]. Membrane separation is a promising t...
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The synthesis of reproducible and continuous AlPO-18 membranes is demonstrated. The separation performance of these membranes for equimolar CO(2)/CH(4) gas mixtures is presented. The AlPO-18 membranes displayed CO(2) permeances as high as ~6.6 × 10(-8) mol m(-2) s Pa with CO(2)/CH(4) separation selectivities in the ~52-60 range at 295 K and 138 kPa.
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Mixed matrix membranes (MMMs) composed of a glassy polymer (polysulfone) and the flexible metal organic framework NH(2)-MIL-53(Al) exhibit excellent separation properties. In contrast to most reported membranes, CO(2)/CH(4) separation selectivity increases with pressure, related to the flexibility of the filler.
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The world market for CO2/CH4 separation using membrane technology is getting bigger and polysulfone (PSf) is one of the most widely investigated polymer membrane materials. However, the existing PSf membranes performances are insufficient to fully exploit these opportunities. Therefore, modification that would produce membrane that fit the needs of target separation performances is a main issue...
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ژورنال
عنوان ژورنال: Separation and Purification Technology
سال: 2019
ISSN: 1383-5866
DOI: 10.1016/j.seppur.2018.11.033